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Unit 3Lesson 4 2 min read

Fuel Cells and Hydrogen Economy

16/18

Learning Objectives

Describe the basic operation of a hydrogen fuel cell.
Write the overall chemical reaction for a hydrogen fuel cell.
Identify the main advantages and challenges of a hydrogen economy.

Clean Power from Hydrogen

A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) directly into electricity through a pair of redox reactions.

How a Hydrogen Fuel Cell Works (PEM Fuel Cell)

Components: Anode, cathode, and an electrolyte membrane (a Proton Exchange Membrane, or PEM).
Reaction at the Anode (-): Hydrogen gas (H₂) is supplied to the anode. A catalyst (usually platinum) splits the H₂ into protons (H⁺) and electrons (e⁻).
2H₂ → 4H⁺ + 4e⁻
Movement: The protons (H⁺) pass through the electrolyte membrane to the cathode. The electrons (e⁻) cannot pass through the membrane, so they are forced to travel through an external circuit, creating an electric current that can power a device.
Reaction at the Cathode (+): Oxygen from the air is supplied to the cathode. The electrons from the external circuit and the protons from the membrane combine with oxygen to form water, which is the only byproduct.
O₂ + 4H⁺ + 4e⁻ → 2H₂O
Overall Reaction: 2H₂ + O₂ → 2H₂O + Electricity + Heat

The Hydrogen Economy

The hydrogen economy is a proposed system of delivering energy using hydrogen.

Concept: Use clean, renewable electricity (from solar or wind) to produce hydrogen gas via the electrolysis of water (the reverse of the fuel cell reaction). Then, use that hydrogen as a clean, portable energy carrier to power vehicles (with fuel cells) or generate electricity when needed.

Advantages and Challenges

Advantages:
Zero Emissions at Point of Use: The only byproduct is water.
High Efficiency: Fuel cells can be more efficient than internal combustion engines.
Energy Security: Hydrogen can be produced domestically from various sources (including water).
Challenges:
Production: Most hydrogen today is produced from natural gas, which releases CO₂. Clean production via electrolysis is currently expensive.
Storage: Storing hydrogen safely and compactly on a vehicle is a major technological hurdle (it's either a high-pressure gas or a cryogenic liquid).
Infrastructure: A whole new infrastructure of hydrogen production plants and fueling stations would need to be built.

Key Terms

Fuel Cell
An electrochemical cell that converts the chemical energy of a fuel and an oxidizing agent directly into electricity. The most common type uses hydrogen and oxygen.
Electrolysis
The process of using electricity to drive a non-spontaneous chemical reaction. The electrolysis of water produces hydrogen and oxygen gas.
Hydrogen Economy
A hypothetical future economy in which the primary energy carrier is hydrogen.
Proton Exchange Membrane (PEM)
A semipermeable membrane generally made from ionomers and designed to conduct protons while acting as an electronic insulator and reactant barrier.

Check Your Understanding

1

What is the only chemical byproduct of a hydrogen-oxygen fuel cell?

2

What is the function of the proton exchange membrane (PEM) in a hydrogen fuel cell?

3

What is considered the biggest challenge to establishing a clean hydrogen economy?